Shear-modulus investigations of monohydroxy alcohols: evidence for a short-chain-polymer rheological response.

نویسندگان

  • C Gainaru
  • R Figuli
  • T Hecksher
  • B Jakobsen
  • J C Dyre
  • M Wilhelm
  • R Böhmer
چکیده

Liquids composed of small-molecule monohydroxy alcohols are demonstrated to display rheological behavior typical for oligomeric chains. This observation was made possible by rheological experiments in which more than seven decades in frequency and more than five decades on the mechanical modulus scale are covered. The singly hydrogen-bonded monohydroxy alcohols were chosen because they display significant, but surprisingly poorly understood effects of intermolecular association. Based on the present shear study, one can apply theoretical concepts of polymer science to understand the anomalous physical behavior of a wide range of hydrogen-bonded liquids.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Rheological characterization of the time and strain dependence for polyisobutylene solutions

The rheological response of polyisobutylene (PIB) solutions in Decalin and a related standard fluid Sl has been charac~~zed in dynamic oscillatory flow, step strain, step-shear rate and steady shear using a Rheometrics RDSII rheometer. The time dependence represented as a discrete spectrum of relaxation times and the strain dependence characterized as an exponential damping function have been p...

متن کامل

Performance Evaluation of Nano-silica Modified Bitumen

In this study, different contents of Nano-silica, 2 wt.%, 4 wt.% and 6 wt.%, have been added to bitumen to modify the physical, mechanical and rheological properties of warm mix asphalt (WMA). WMA is containing 2 wt.% of Sasobit (mixture of long-chain hydrocarbons). Various quality control tests have been carried out to characterize the modified bitumen and WMA. The rheo...

متن کامل

Rheological properties of modified Bitumen: Comparison of waste polymers’ performance

In this investigation, rheological properties of three different polymer-modified bitumen compounds containing recycled polyethylene terephthalate (R-PET), crumb rubber (CR) and poly (styrene-butadiene-styrene) (SBS) are evaluated and compared. The modified samples were tested by a dynamic shear rheometer (DSR) where complex modulus (G*), phase angle (δ) and rutting resistance (G*/Sinδ) of spec...

متن کامل

Performance Evaluation of SBS/sulfur Modified Bitumen and its Effect on Fuel Resistance

The fuel resistance property plays an important role in asphalts, but available standards for determining this characteristic are presently lacking. In the present work, a number of polymer modified bitumen with styrene-butadiene-styrene (SBS) polymer (4, 5, 6% SBS) and SBS/ sulfur modified bitumen with various percentages of sulfur (1.65, 3, 3.5% based on polymer content) were prepared. Each s...

متن کامل

مطالعه پارامترهای موثر بر خواص مکانیکی پیشرانه جامد مرکب بر پایه HTPB/Al/AP

The success of the composite solid propellant motor depends on the proper stress-strain behavior of the propellant grain against tensile, compression and shear stresses and intensive changes in gravity during launch. In this paper, the effect of formulation components and other parameters affecting mechanical properties (tensile strength, elongation and elastic modulus), and their effects AP/Al...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:
  • Physical review letters

دوره 112 9  شماره 

صفحات  -

تاریخ انتشار 2014